Yii2: Config params vs. constants

When should I use what?

I have the option to define constants in the index.php entry script file like it is recommended in Yii2 guide: constants. Or I could use the params in the configuration - explained in YII2 guide: params. Both are per application and not really global.

Currently it seems to me that params are a bit less comfortable if I want to combine values like this:

define('SOME_URL',            'http://some.url');
define('SOME_SPECIALIZED_URL', SOME_URL . '/specialized');

Besides, accessing is bit more code (Yii::$app->params['something']) compared to constants.

So when should or could I use what?